Metal-free radical oxidative alkoxycarbonylation and imidation of alkanes.
نویسندگان
چکیده
A metal-free radical oxidative carbonylation of alkanes is demonstrated, yielding esters and imides by means of di-tert-butylperoxide as an oxidant. Various alkanes, alcohols and amides were compatible in this system generating the desired carbonyl products in up to 86% yields. We proposed a plausible radical cross-coupling process based on the preliminary mechanistic studies.
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عنوان ژورنال:
- Chemical communications
دوره 53 51 شماره
صفحات -
تاریخ انتشار 2017